Publikationen

Formation of RuO2 nanoparticles by thermal decomposition of Ru(NO)(NO3)(3)

Autor(en)
Zeljka Petrovic, Mira Ristic, Marijan Marcius, Bogdan Sepiol, Herwig Peterlik, Mile Ivanda, Svetozar Music
Abstrakt

A simple one-pot synthesis of RuO

2 nanoparticles by the thermal decomposition of ruthenium nitrosyl nitrate [Ru(NO)(NO

3)

3] up to 800 °C was investigated. The RuO

2 phase was characterized by XRD, SAXS, FE SEM/EDS, Raman, DTA/TGA and FT-IR techniques. Broadening of prominent diffraction lines (110), (101) and (211) was used to estimate nanocrystallite sizes in RuO

2 particles. FE SEM showed the formation of RuO

2 plates at 400 °C which consisted of RuO

2 nanoparticles of about 15-25 nm in size. At 800 °C RuO

2 nanoparticles showed the sintering effect and some of them increased in size to about 200 nm. Raman and FT-IR spectra consolidated the findings. Moreover, DTA curves showed the decomposition and release of NO and NO

3

- groups to be a stepwise process.

Organisation(en)
Dynamik Kondensierter Systeme
Externe Organisation(en)
Rudjer Boskovic Institute
Journal
Ceramics International
Band
41
Seiten
7811-7815
Anzahl der Seiten
5
ISSN
0272-8842
DOI
https://doi.org/10.1016/j.ceramint.2015.02.115
Publikationsdatum
07-2015
Peer-reviewed
Ja
ÖFOS 2012
103018 Materialphysik
Schlagwörter
ASJC Scopus Sachgebiete
Electronic, Optical and Magnetic Materials, Ceramics and Composites, Materials Chemistry, Surfaces, Coatings and Films, Process Chemistry and Technology
Link zum Portal
https://ucris.univie.ac.at/portal/de/publications/formation-of-ruo2-nanoparticles-by-thermal-decomposition-of-runono33(2b0a4de5-f2ce-42a9-bd76-9022ae2beffe).html