Publications
Porous titanium and zirconium oxo carboxylates at the interface between sol-gel and metal-organic framework structures
- Author(s)
- Christian Maurer, Bettina Baumgartner, Silvia Pabisch, Johanna Akbarzadeh, Herwig Peterlik, Ulrich Schubert
- Abstract
Reaction of Ti(OiPr)4 with several tri- and
tetracarboxylic acids, followed by hydrolysis, resulted in microporous,
structured materials, with microporous surface areas up to 340 m2 g−1. Depending on the kind of carboxylic acid, the Ti:COOH ratio and the Ti:H2O
ratio, either pillared layered or surface fractal 3D structures were
obtained according to SAXS measurements. The most pronounced layered
structure was found for 1,2,4,5-benzenetetrabenzoic acid and a Ti:H2O ratio of 4, while a Ti:H2O
ratio of 2 resulted in a 3D structure. The use of
1,3,5-benzenetricarboxylic acid or 1,3,5-benzenetribenzoic acid resulted
in similar structures which, however, were less pronounced and less
ordered. The reaction of tetrakis(4-carboxyphenyl)silicon with Ti(OiPr)4 or benzenetribenzoic acid with Zr(OiPr)4 gave 3D structures for all Ti:H2O ratios.
- Organisation(s)
- Dynamics of Condensed Systems
- External organisation(s)
- Technische Universität Wien
- Journal
- Dalton Transactions
- Volume
- 43
- Pages
- 950-957
- No. of pages
- 8
- ISSN
- 1477-9226
- DOI
- https://doi.org/10.1039/c3dt51285a
- Publication date
- 01-2014
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104003 Inorganic chemistry, 103015 Condensed matter
- Keywords
- ASJC Scopus subject areas
- Inorganic Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/de2e1429-16b7-4cfb-a1fb-4109b9bc3f86