Severe Plastic Deformation of Ceramics by High-Pressure Torsion: Review of Principles and Applications

Author(s)

Kaveh Edalati, Jacqueline Hidalgo-Jiménez, Thanh Tam Nguyen, Hadi Sena, Nariman Enikeev, Gerda Rogl, Valery I. Levitas, Zenji Horita, Michael J. Zehetbauer, Ruslan Z. Valiev, Terence G. Langdon

Abstract

Ceramics are typically brittle at ambient conditions due to their covalent or ionic bonding and limited dislocation activities. While plasticity, and occasionally superplasticity, can be achieved in ceramics at high temperatures through thermally activated phenomena, creep, and grain boundary sliding, their deformation at ambient temperature and pressure remains challenging. Processing under high pressure via the high-pressure torsion (HPT) method offers new pathways for severe plastic deformation (SPD) of ceramics. This article reviews recent advances in HPT processing of ceramics, focusing primarily on traditional ceramics (e.g., oxides, carbides, nitrides, oxynitrides) and to a lesser extent advanced ceramics (e.g., silicon, carbon, perovskites, clathrates). Key structural and microstructural features of SPD-processed ceramics are discussed, including phase transformations and the generation of nanograins and defects such as vacancies and dislocations. The properties and applications of these deformed ceramics are summarized, including powder consolidation, photoluminescence, bandgap narrowing, photovoltaics, photocatalysis (dye degradation, plastic waste degradation, antibiotic degradation, hydrogen production, CO₂ conversion), electrocatalysis, thermoelectric performance, dielectric performance, and ion conductivity for Li-ion batteries. Additionally, the article highlights the role of HPT in synthesizing novel materials, such as high-entropy ceramics (particularly high-entropy oxides), black oxides, and high-pressure polymorphs, which hold promise for energy and environmental applications.

Organisation(s)

Department of Materials Chemistry, Dynamics of Condensed Systems, Physics of Nanostructured Materials

External organisation(s)

Kyushu University, Stanford University, Ufa University of Science and Technology, Saint Petersburg State University, Saint Petersburg State Marine Technical University, Iowa State University, Kyushu Institute of Technology, Kumamoto University, Saga University, University of Southampton, University of Southern California

Journal

Annual Review of Materials Research

Volume

55

Pages

89-124

No. of pages

36

ISSN

1531-7331

DOI

https://doi.org/10.1146/annurev-matsci-080423-122701

Publication date

07-2025

Peer reviewed

Yes

Austrian Fields of Science 2012

103018 Materials physics, 104011 Materials chemistry, 205019 Material sciences

Keywords

ASJC Scopus subject areas

General Materials Science

Sustainable Development Goals

SDG 7 - Affordable and Clean Energy

Portal url

https://ucrisportal.univie.ac.at/en/publications/25657429-6e73-446e-b1b1-9dccf51ba72c